全文获取类型
收费全文 | 28640篇 |
免费 | 4106篇 |
国内免费 | 2666篇 |
专业分类
化学 | 19635篇 |
晶体学 | 263篇 |
力学 | 1900篇 |
综合类 | 273篇 |
数学 | 3265篇 |
物理学 | 10076篇 |
出版年
2024年 | 28篇 |
2023年 | 568篇 |
2022年 | 528篇 |
2021年 | 793篇 |
2020年 | 1098篇 |
2019年 | 1055篇 |
2018年 | 874篇 |
2017年 | 776篇 |
2016年 | 1224篇 |
2015年 | 1170篇 |
2014年 | 1477篇 |
2013年 | 1983篇 |
2012年 | 2560篇 |
2011年 | 2657篇 |
2010年 | 1646篇 |
2009年 | 1632篇 |
2008年 | 1736篇 |
2007年 | 1659篇 |
2006年 | 1489篇 |
2005年 | 1227篇 |
2004年 | 940篇 |
2003年 | 766篇 |
2002年 | 692篇 |
2001年 | 536篇 |
2000年 | 518篇 |
1999年 | 607篇 |
1998年 | 557篇 |
1997年 | 544篇 |
1996年 | 615篇 |
1995年 | 502篇 |
1994年 | 457篇 |
1993年 | 384篇 |
1992年 | 362篇 |
1991年 | 316篇 |
1990年 | 247篇 |
1989年 | 201篇 |
1988年 | 157篇 |
1987年 | 135篇 |
1986年 | 125篇 |
1985年 | 118篇 |
1984年 | 87篇 |
1983年 | 60篇 |
1982年 | 41篇 |
1981年 | 36篇 |
1980年 | 17篇 |
1978年 | 19篇 |
1977年 | 23篇 |
1976年 | 20篇 |
1975年 | 28篇 |
1974年 | 27篇 |
排序方式: 共有10000条查询结果,搜索用时 23 毫秒
61.
62.
Dr. Wan‐Ling Liu Ni‐Shin Yang Ya‐Ting Chen Stephen Lirio Cheng‐You Wu Prof. Chia‐Her Lin Prof. Hsi‐Ya Huang 《Chemistry (Weinheim an der Bergstrasse, Germany)》2015,21(1):115-119
A green and sustainable strategy synthesizes clinical medicine warfarin anticoagulant by using lipase‐supported metal–organic framework (MOF) bioreactors (see scheme). These findings may be beneficial for future studies in the industrial production of chemical, pharmaceutical, and agrochemical precursors. 相似文献
63.
64.
65.
Here, we report a new strategy for rapid synthesis of branched peptide by side-chain hydrazide ligation at Asn. The hydrazide was converted to thioester at Asn side chain by NaNO2 and thiol reagent, and sequential ligation with an N-terminus Cys-peptide efficiently afforded the branched peptide. A branched cyclic peptide was successfully synthesized by side-chain ligation with a two-Cys-peptide and formation of a disulfide bond. This approach provides a new way for expeditious synthesis of branched peptides and facilitates the design of neopeptides as functional bio-mimics. 相似文献
66.
67.
68.
Highly fluorescent polycaprolactones decorated with di(thiophene‐2‐yl)‐diketopyrrolopyrrole: A covalent strategy of tuning fluorescence properties in solid states 下载免费PDF全文
Kai Wang Yimin Luo Shuo Huang Hongbin Yang Bin Liu Mingfeng Wang 《Journal of polymer science. Part A, Polymer chemistry》2015,53(8):1032-1042
Well‐defined 1,4‐diketo‐3,6‐di(thiophen‐2‐yl)pyrrolo[3,4‐c]pyrrole (DTDPP) labeled polycaprolactones (PCL) with different chain lengths were synthesized and characterized. The effect of polymer chain lengths on the optical properties of DTDPP in solid states was studied by UV‐Vis absorption spectroscopy as well as steady‐state and dynamic fluorescence spectroscopies. Our results indicate that when the PCL side chain is extended to a certain length, the intermolecular aggregation of DTDPP units can be reduced significantly due to segregation effect of PCL. This approach offers a new facile strategy to address the common problem of aggregation‐caused quenching existing in organic fluorophores. These highly fluorescent biodegradable PCL polymers may find broad biomedical applications such as fluorescence‐based bioimaging and tissue engineering. © 2015 Wiley Periodicals, Inc. J. Polym. Sci. Part A: Polym. Chem. 2015 , 53, 1032–1042 相似文献
69.
70.
Zihao Yang Junzhi Cui Yufeng Nie Zhiqiang Huang Meizhen Xiang 《Acta Mechanica Sinica》2015,31(5):762-776
In this paper,a statistical second-order twoscale(SSOTS) method is developed to simulate the dynamic thcrmo-mechanical performances of the statistically inhomogeneous materials.For this kind of composite material,the random distribution characteristics of particles,including the shape,size,orientation,spatial location,and volume fractions,are all considered.Firstly,the repre.sentation for the microscopic configuration of the statistically inhomogeneous materials is described.Secondly,the SSOTS formulation for the dynamic thermo-mechanical coupled problem is proposed in a constructive way,including the cell problems,effective thermal and mechanical parameters,homogenized problems,and the SSOTS formulas of the temperatures,displacements,heat flux densities and stresses.And then the algorithm procedure corresponding to the SSOTS method is brought forward.The numerical results obtained by using the SSOTS algorithm are compared with those by classical methods.In addition,the thermo-mechanical coupling effect is studied by comparing the results of coupled case with those of uncoupled case.It demonstrates that the coupling effect on the temperatures,heat flux densities,displacements,and stresses is very distinct.The results show that the SSOTS method is valid to predict the dynamic thermo-mechanical coupled performances of statistically inhomogeneous materials. 相似文献